Search results for "chemistry [Water]"
showing 10 items of 2369 documents
Dynamics of ice mass deformation: Linking processes to rheology, texture, and microstructure
2013
[1] Prediction of glacier and polar ice sheet dynamics is a major challenge, especially in view of changing climate. The flow behavior of an ice mass is fundamentally linked to processes at the grain and subgrain scale. However, our understanding of ice rheology and microstructure evolution based on conventional deformation experiments, where samples are analyzed before and after deformation, remains incomplete. To close this gap, we combine deformation experiments with in situ neutron diffraction textural and grain analysis that allows continuous monitoring of the evolution of rheology, texture, and microstructure. We prepared ice samples from deuterium water, as hydrogen in water ice has …
First simultaneous mercury and major volatiles characterization of atmospheric hydrothermal emissions at the Pisciarelli's fumarolic system (Campi Fl…
2020
Abstract Hydrothermal systems with active surface expressions are important natural source of atmospheric mercury. Here we report on the first simultaneous assessment of gaseous elemental mercury (GEM) and major volatiles (H2S and CO2) fluxes from the fumarolic system of Pisciarelli, currently the most active at the Campi Flegrei caldera (CFc), Naples (Italy). This was achieved via a GPS-synchronized Lumex and MultiGAS survey which extends similar investigations reported elsewhere. GEM concentrations measured in the fumarolic emissions were consistently above background air level close to the degassing area (mean ~ 8 ± 3 ng m−3 on average) and ranged up to 12,000 ng m−3. Our data evidenced …
Holocene surface ruptures of the Rurrand Fault, Germany—insights from palaeoseismology, remote sensing and shallow geophysics
2016
The Lower Rhine Embayment in Central Europe hosts a rift system that has very low deformation rates. The faults in this area have slip rates of less than 0.1 mm/yr, which does not allow to investigate ongoing tectonic deformation with geodetic techniques, unless they cover very long time spans. Instrumental seismicity does only cover a small fraction of the very long earthquake recurrence intervals of several thousands of years. Paleoseismological studies are needed to constrain slip rates and the earthquake history of such faults. Destructive earthquakes are rare in the study area, but did occur in historic times. In 1755/56, a series of strong earthquakes caused significant destruction in…
Late Paleozoic Ice Age glaciers shaped East Antarctica landscape
2019
International audience; The erosion history of Antarctica is fundamental to our understanding of interlinks between climate and glacier dynamics. However, because of the vast polar ice sheet covering more than 99% of Antarctica land mass, the continental surface response to glacial erosion remains largely unknown. Over the last decade the subglacial topography of Antarctica has been imaged by airborne radar surveys. These studies revealed high and complex sub-glacial relief in the core of the East Antarctic shield, interpreted as resulting from rifting episodes and low long-term erosion rates, or repeated large-scale glacial retreats and advances. In East Antarctica, thermochronology studie…
Pressure-temperature evolution during two granulite-facies metamorphic events (2.62 and 2.02 Ga) in rocks from the Central Zone of the Limpopo Belt, …
2018
Abstract The Central Zone of the Limpopo Belt in southern Africa is a classical example of a polymetamorphic terrane that experienced three metamorphic events at 3.22 Ga (M1), 2.66–2.61 Ga (M2) and 2.02 (M3). However, the geodynamic significance of these events is controversial as their P-T evolution was poorly constrained. We present new petrological and geochronological data for the M2 and M3 events. The Neoarchean M2 event is well-preserved in samples from a newly discovered enclave of supracrustal and magmatic rocks in the 2.612 Ga Bulai pluton that shielded the enclave against a Paleoproterozoic M3 overprint, which is dominant in rocks exposed outside the pluton. P-T pseudosection mode…
The relationship between eruptive activity, flank collapse, and sea level at volcanic islands: A long-term (>1 Ma) record offshore Montserrat, Les…
2016
Hole U1395B, drilled southeast of Montserrat during Integrated Ocean Drilling Program Expedition 340, provides a long (>1 Ma) and detailed record of eruptive and mass-wasting events (>130 discrete events). This record can be used to explore the temporal evolution in volcanic activity and landslides at an arc volcano. Analysis of tephra fall and volcaniclastic turbidite deposits in the drill cores reveals three heightened periods of volcanic activity on the island of Montserrat (∼930 to ∼900 ka, ∼810 to ∼760 ka, and ∼190 to ∼120 ka) that coincide with periods of increased volcano instability and mass-wasting. The youngest of these periods marks the peak in activity at the Soufriere Hills vol…
Advances in Fourier transform infrared spectroscopy of natural glasses: From sample preparation to data analysis
2014
Fourier transform infrared spectroscopy (FTIR) is an analytical technique utilized to measure the concentrations of H and C species in volcanic glasses. Water and CO2 are the most abundant volatile species in volcanic systems. Water is present in magmas in higher concentrations than CO2 and is also more soluble at lower pressures, and, therefore it is the dominant volatile forming bubbles during volcanic eruptions. Dissolved water affects both phase equilibria and melt physical properties such as density and viscosity, therefore, water is important for understanding magmatic processes. Additionally, quantitative measurements of different volatile species using FTIR can be achieved at high s…
Vegetation and environmental changes in tropical South America from the last glacial to the Holocene documented by multiple cave sediment proxies
2019
Abstract δ 18 O values in speleothems have been utilized to document past changes in South American monsoon intensity. However, changes in regional vegetation and ecosystems have not been part of this discussion, and other cave proxies such as speleothem δ 13 C values, a useful proxy for vegetation reconstruction, have been neglected due to interpretive complexities. Here we report δ 13 C values and 87Sr/86Sr ratios in stalagmites, together with XRF-derived elemental chemistry, δ 13 Corg values and carbon content from a sedimentary profile from the same cave where the stalagmites were collected. In combination with a previously published δ 18 O record, this enables us to clarify climate and…
Characterisation and origin of hydrothermal waters at São Miguel (Azores) inferred by chemical and isotopic composition
2017
Abstract This study focuses on the characterisation and origin of hydrothermal waters discharging from three main active volcanoes (Furnas, Fogo and Sete Cidades) at Sao Miguel, where 33 water with temperatures ranging between 13 and 97 °C, and 5 precipitate samples were collected. The developed conceptual model for this active hydrothermal system reveals that all waters can be classified by Na-HCO 3 , Na-Cl and Na-SO 4 types and are of meteoric origin. This is confirmed by the stable hydrogen and oxygen isotope data that are positioned close to the local meteoric water line (− 4.1‰ ≤ δ 18 O H2O ≤ 5.2‰; − 17.6‰ ≤ δD H2O ≤ 20.4‰), except for the Na-Cl type water at Ferraria (Sete Cidades a…
Subduction metamorphism in the Himalayan ultrahigh-pressure Tso Morari massif: an integrated geodynamic and petrological modelling approach
2017
The Tso Morari massif is one of only two regions where ultrahigh-pressure (UHP) metamorphism of subducted crust has been documented in the Himalayan Range. The tectonic evolution of the massif is enigmatic, as reported pressure estimates for peak metamorphism vary from ∼2.4 GPa to ∼4.8 GPa. This uncertainty is problematic for constructing large-scale numerical models of the early stages of India–Asia collision. To address this, we provide new constraints on the tectonothermal evolution of the massif via a combined geodynamic and petrological forward-modelling approach. A prograde-to-peak pressure–temperature–time (P–T–t) path has been derived from thermomechanical simulations tailored for E…